What happens
Yolk lecithin helps coat tiny oil droplets so they remain dispersed in the water phase.
Egg science
An egg is rarely present for just one reason. Find its main job first, then understand what heat, whisking and substitutions will change.
Function finder
The same egg behaves differently depending on which part is used, how it is mixed and how it is heated.
Main job
Yolk lecithin helps coat tiny oil droplets so they remain dispersed in the water phase.
Adding oil too quickly overwhelms the developing emulsion and the sauce splits.
A suitable emulsifier such as mustard or added lecithin may help, but flavour and stability change.
Inside the shell
These structures protect the contents, keep the yolk suspended and change as the egg ages. The proportions vary naturally from egg to egg.

The working ingredient
A cake may use eggs for emulsification, aeration, moisture, colour and structure at the same time. That is why replacing several eggs is harder than replacing one.
Heat unfolds egg proteins so they join into a network. That network turns liquid mixtures into scrambled eggs, custards, curds and set fillings.
The same protein network connects other ingredients, helping patties, meatballs, stuffings and baked goods keep their shape.
Lecithin and other yolk components help oil and water remain dispersed, giving mayonnaise and hollandaise their smooth, stable texture.
Whisked white proteins surround air bubbles. Heat then sets the bubbles into meringues, soufflés and airy cakes.
Water, yolk fat and proteins add tenderness, richness and a fuller mouthfeel to doughs, batters, sauces and fillings.
Whole egg or yolk wash helps pastry brown and shine. White gives a paler, crisper finish; yolk gives deeper colour.
As egg-white proteins coagulate, they trap suspended particles. This is used to clarify stocks and some drinks.
Substitution logic
No substitute is a universal egg. The more eggs a recipe contains, and the more jobs they perform, the less likely a simple swap is to reproduce the original.
Useful in patties, cookies and some quick breads. Results vary in colour, flavour and firmness.
Useful where whipped white supplies air. It does not necessarily set or brown like egg protein.
Can work in forgiving bakes, but may add sweetness, acidity, flavour or density.
Choice depends on whether the recipe is a cold sauce, batter or baked emulsion.
Food allergy: an “egg replacer” is not necessarily egg-free, and products sold as egg substitutes may contain egg white. Check the ingredient and allergen label every time.
Failure diagnosis
Most failures come from temperature, mixing, ingredient order or asking a substitute to do a job it cannot perform.
Likely cause: Fat or yolk has interfered with the foam, or the bowl is greasy.
Next time: Use a scrupulously clean bowl, separate each egg over a spare bowl and add sugar gradually after a foam forms.
Likely cause: Sugar may be undissolved, the foam overbeaten or the meringue undercooked or stored in humidity.
Next time: Rub a little mixture between your fingers to check sugar has dissolved, stop at the required peak and follow the recipe’s drying time.
Likely cause: Oil was added faster than the yolk could surround its droplets, or the ingredients were poorly combined.
Next time: Begin with a fresh yolk or a teaspoon of water in a clean bowl, then whisk the split mixture into it very slowly.
Likely cause: Excess heat tightened the protein network until it squeezed out water.
Next time: Use gentler heat, stir continuously and stop before boiling. A water bath moderates oven heat.
Likely cause: Too little incorporated air, overmixing after flour, or an unsuitable egg substitute reduced lift and structure.
Next time: Use the stated egg size, aerate as directed and choose a substitute that can perform the recipe’s main function.
Likely cause: Some settling is normal; a weak foam, heavy mixing or under-set structure makes it more dramatic.
Next time: Fold gently, bake promptly and set the structure before opening the oven.
Technical references